The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / t-C4H9O2,(CH3)3CO2 / Lightfoot(1990)_298K_210-280nm

DATAFILE: t-C4H9O2,(CH3)3CO2_Lightfoot(1990)_298K_210-280nm.txt
NAME: 1,1,1-dimethylethylperoxy radical, tert-butylperoxy radical
FORMULA: t-C4H9O2,(CH3)3CO2
AUTHOR(YEAR): Lightfoot(1990)
T: 298K
λ: 210-280nm
BIBLIOGRAPHY: P.D. Lightfoot, P. Roussel, B. Veyret, and R. Lesclaux, "Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals", J. Chem.Soc. Faraday Trans. 86, 2927-2936 (1990); DOI: 10.1039/FT9908602927
COMMENTS: Original values calibrated to the CH3O2 spectrum reported by

G.K. Moortgat, B. Veyret, and R. Lesclaux, "Absorption spectrum and kinetics of reactions of the acetylperoxy radical," J. Phys. Chem. 93, 2362-2368 (1989),

P.D. Lightfoot, R. Lesclaux, and B. Veyret, "Flash photolysis study of the CH3O2 + CH3O2 reaction: Rate constants and branching ratios from 248 to 573 K", J. Phys. Chem. 94, 700-707 (1990), and

P. D. Lightfoot, B. Veyret and R. Lesclaux, "Flash photolysis study of the CH3O2 + HO2 reaction between 248 and 573 K", J. Phys. Chem. 94, 708-714 (1990)

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